Monday 25 November 2013

Module IV - Global Warming - Greenhouse gases


Global warming refers to the increase in the average temperature of the Earth's near-surface air and oceans in recent decades and its projected continuation.
The measured global average air temperature near the Earth's surface rose 0.74 ± 0.18 °C (1.33 ± 0.32 °F) during the last 100 years. The Intergovernmental Panel on Climate Change (IPCC) concludes, "most of the observed increase in globally averaged temperatures since the mid-20th century is very likely due to the observed increase in anthropogenic greenhouse gas concentrations" via the greenhouse effect. Natural phenomena such as solar variation combined with volcanoes probably had a small warming effect from pre-industrial times to 1950 and a small cooling effect from 1950 onward. These basic conclusions have been endorsed by at least 30 scientific societies and academies of science, including all of the national academies of science of the major industrialized countries. However, a few individual scientists disagree with some of the main conclusions of the IPCC.
Climate models referenced by the IPCC project that global surface temperatures are likely to increase by 1.1 to 6.4 °C (2.0 to 11.5 °F) between 1990 and 2100. The range of values results from the use of differing scenarios of future greenhouse gas emissions as well as models with differing climate sensitivity. Although most studies focus on the period up to 2100, warming and sea level rise are expected to continue for more than a millennium even if greenhouse gas levels are stabilized. This reflects the large heat capacity of the oceans.
An increase in global temperatures is expected to cause other changes, including sea level rise, increased intensity of extreme weather events, and changes in the amount and pattern of precipitation. Other effects of global warming include changes in agricultural yields, glacier retreat, species extinctions and increases in the ranges of disease vectors.
Remaining scientific uncertainties include the amount of warming expected in the future, and how warming and related changes will vary from region to region around the globe. There is ongoing political and public debate worldwide regarding what, if any, action should be taken to reduce or reverse future warming or to adapt to its expected consequences. Most national governments have signed and ratified the Kyoto Protocol, aimed at reducing greenhouse gas emissions.
Causes : Green House Gases and Green House Effects, Solar Variation.

Greenhouse gases
Greenhouse gases are components of the atmosphere that contribute to the greenhouse effect. Some greenhouse gases occur naturally in the atmosphere, while others result from human activities such as burning of fossil fuels such as coal. Greenhouse gases include water vapor, carbon dioxide, methane, nitrous oxide, and ozone.
When sunlight reaches the surface of the Earth, some of it is absorbed and warms the surface. Because the Earth's surface is much cooler than the sun, it radiates energy at much longer wavelengths than does the sun. The atmosphere absorbs these longer wavelengths more effectively than it does the shorter wavelengths from the sun. The absorption of this longwave radiant energy warms the atmosphere; the atmosphere also is warmed by transfer of sensible and latent heat from the surface. Greenhouse gases also emit longwave radiation both upward to space and downward to the surface. The downward part of this longwave radiation emitted by the atmosphere is the "greenhouse effect." The term is a misnomer, as this process is not the mechanism that warms greenhouses.
The major greenhouse gases are water vapor, which causes about 36-70% of the greenhouse effect on Earth (not including clouds); carbon dioxide, which causes 9-26%; methane, which causes 4-9%, and ozone, which causes 3-7%. It is not possible to state that a certain gas causes a certain percentage of the greenhouse effect, because the influences of the various gases are not additive. Other greenhouse gases include, but are not limited to, nitrous oxide, sulfur hexafluoride, hydrofluorocarbons, perfluorocarbons and chlorofluorocarbons. The major atmospheric constituents (nitrogen, N2 and oxygen, O2) are not greenhouse gases. This is because homonuclear diatomic molecules such as N2 and O2 neither absorb nor emit infrared radiation, as there is no net change in the dipole moment of these molecules when they vibrate. Molecular vibrations occur at energies that are of the same magnitude as the energy of the photons on infrared light. Heteronuclear diatomics such as CO or HCl absorb IR; however, these molecules are short-lived in the atmosphere owing to their reactivity and solubility. As a consequence they do not contribute significantly to the greenhouse effect.
Late 19th century scientists experimentally discovered that N2 and O2 did not absorb infrared radiation (called, at that time, "dark radiation") and that CO2 and many other gases did absorb such radiation. It was recognized in the early 20th century that the known major greenhouse gases in the atmosphere caused the earth's temperature to be higher than it would have been without the greenhouse gases.

Anthropogenic greenhouse gases
The concentrations of several greenhouse gases have increased over time. Human activity increases the greenhouse effect primarily through release of carbon dioxide, but human influences on other greenhouse gases can also be important. Some of the main sources of greenhouse gases due to human activity include: burning of fossil fuels and deforestation leading to higher carbon dioxide concentrations; livestock and paddy rice farming, land use and wetland changes, pipeline losses, and covered vented landfill emissions leading to higher methane atmospheric concentrations. According to the Food and Agriculture Organization of the United Nations, the livestock industry is responsible for 18 percent of greenhouse gas emissions measured in CO2 equivalent, a higher share than transportation. Many of the newer style fully vented septic systems that enhance and target the fermentation process also are major sources of atmospheric methane;
use of chlorofluorocarbons (CFCs) in refrigeration systems, and use of CFCs and halons in fire suppression systems and manufacturing processes.
Agricultural activities, including the use of fertilizers, that lead to higher nitrous oxide concentrations.
The seven sources of CO2 from fossil fuel combustion are (with percentage contributions for 2000-2004): Solid fuels (e.g. coal): 35% Liquid fuels (e.g. gasoline): 36% Gaseous fuels (e.g. natural gas): 20% Flaring gas industrially and at wells: <1% Cement production: 3% Non-fuel hydrocarbons: <1%  The "international bunkers" of shipping and air transport not included in national inventories: 4%
Greenhouse gas emissions from industry, transportation and agriculture are very likely the main cause of recently observed global warming. Major sources of an individual's GHG include home heating and cooling, electricity consumption, and transportation. Corresponding conservation measures are improving home building insulation, cellular shades, compact fluorescent lamps and choosing high miles per gallon vehicles.
Carbon dioxide, methane, nitrous oxide and three groups of fluorinated gases (sulfur hexafluoride, HFCs, and PFCs) are the major greenhouse gases and the subject of the Kyoto Protocol, which entered into force in 2005.
CFCs, although greenhouse gases, are regulated by the Montreal Protocol, which was motivated by CFCs' contribution to ozone depletion rather than by their contribution to global warming. Note that ozone depletion has only a minor role in greenhouse warming though the two processes often are confused in the popular media.


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