Monday, 25 November 2013

Module V - Water Pollution - part I

Notes on Water

Water resources are sources of water that are useful or potentially useful to humans. Water is essential for all forms of life, and this is no different for people. Many uses of water include agricultural, industrial, household, recreational and environmental activities. Virtually all of these human uses require fresh water. 88.7% of water on the Earth is salt water, and over two thirds of fresh water is frozen in glaciers and polar ice caps, leaving only 0.9% available for human use. Fresh water is a renewable resource, yet the world's supply of clean, fresh water is steadily decreasing. Water demand already exceeds supply in many parts of the world, and as world population continues to rise at an unprecedented and unsustainable rate, many more areas are expected to experience this imbalance in the near future. The framework for allocating water resources to water users (where such a framework exists) is known as water rights.

Surface water
Surface water is water in a river, lake or fresh water wetland. Surface water is naturally replenished by precipitation and naturally lost through discharge to the oceans, evaporation, and sub-surface seepage.
Although the only natural input to any surface water system is precipitation within its watershed, the total quantity of water in that system at any given time is also dependent on many other factors. These factors include storage capacity in lakes, wetlands and artificial reservoirs, the permeability of the soil beneath these storage bodies, the runoff characteristics of the land in the watershed, the timing of the precipitation and local evaporation rates. All of these factors also affect the proportions of water lost.
Human activities can have a large impact on these factors. Humans often increase storage capacity by constructing reservoirs and decrease it by draining wetlands. Humans often increase runoff quantities and velocities by paving areas and channelizing stream flow.
The total quantity of water available at any given time is an important consideration. Some human water users have an intermittent need for water. For example, many farms require large quantities of water in the spring, and no water at all in the winter. To supply such a farm with water, a surface water system may require a large storage capacity to collect water throughout the year and release it in a short period of time. Other users have a continuous need for water, such as a power plant that requires water for cooling. To supply such a power plant with water, a surface water system only needs enough storage capacity to fill in when average stream flow is below the power plant's need.
Nevertheless, over the long term the average rate of precipitation within a watershed is the upper bound for average consumption of natural surface water from that watershed.
Natural surface water can be augmented by importing surface water from another watershed through a canal or pipeline. It can also be artificially augmented from any of the other sources listed here, however in practice the quantities are negligible. Humans can also cause surface water to be "lost" (i.e. become unusable) through pollution.

Sub-surface water
Sub-Surface water, or groundwater, is fresh water located in the pore space of soil and rocks. It is also water that is flowing within aquifers below the water table. Sometimes it is useful to make a distinction between sub-surface water that is closely associated with surface water and deep sub-surface water in an aquifer (sometimes called "fossil water").
Sub-surface water can be thought of in the same terms as surface water: inputs, outputs and storage. The critical difference is that due to its slow rate of turnover, sub-surface water storage is generally much larger compared to inputs than it is for surface water. This difference makes it easy for humans to use sub-surface water unsustainably for a long time without severe consequences. Nevertheless, over the long term the average rate of seepage above a sub-surface water source is the upper bound for average consumption of water from that source.
The natural input to sub-surface water is seepage from surface water. The natural outputs from sub-surface water are springs and seepage to the oceans.
If the surface water source is also subject to substantial evaporation, a sub-surface water source may become saline. This situation can occur naturally under endorheic bodies of water, or artificially under irrigated farmland. In coastal areas, human use of a sub-surface water source may cause the direction of seepage to ocean to reverse which can also cause soil salinization. Humans can also cause sub-surface water to be "lost" (i.e. become unusable) through pollution. Humans can increase the input to a sub-surface water source by building reservoirs or detention ponds.

Water in the ground is in sections called aquifers. Rain rolls down and comes into these. Normally an aquifer is near to the equilibrium in its water content. The water content of an aquifier normally depends on the grain sizes. This means that the rate of extraction may be limited by poor permeability.

a)What are the sources of water pollution?

Some of the principal sources of water pollution are: Geology of aquifers from which groundwater is abstracted, Industrial discharge of chemical wastes and byproducts, Discharge of poorly-treated or untreated sewage, Surface runoff containing pesticides or fertilizers, Slash and burn farming practice, which is often an element within shifting cultivation agricultural systems, Surface runoff containing spilled petroleum products, Surface runoff from construction sites, farms, or paved and other impervious surfaces e.g. silt, Discharge of contaminated and/or heated water used for industrial processes.

Acid rain caused by industrial discharge of sulphur dioxide (by burning high-sulphur fossil fuels), Excess nutrients are added (eutrophication) by runoff containing detergents or fertilizers, Underground storage tank leakage, leading to soil contamination, and hence aquifer contamination, Inappropriate disposal of various solid wastes and, on a localized scale, littering, Oil spills.

There are many causes for water pollution but two general categories exist: direct and indirect contaminant sources.
Direct sources include effluent outfalls from factories, refineries, waste treatment plants etc.. that emit fluids of varying quality directly into urban water supplies. In the United States and other countries, these practices are regulated, although this doesn't mean that pollutants can't be found in these waters.
Indirect sources include contaminants that enter the water supply from soils/groundwater systems and from the atmosphere via rain water. Soils and groundwaters contain the residue of human agricultural practices (fertilizers, pesticides, etc..) and improperly disposed of industrial wastes. Atmospheric contaminants are also derived from human practices (such as gaseous emissions from automobiles, factories and even bakeries).
Contaminants can be broadly classified into organic, inorganic, radioactive and acid/base. Examples from each class and their potential sources are too numerous to discuss here.

b)What are the effects of water pollution?

The effects of water pollution are varied. They include poisonous drinking water, poisionous food animals (due to these organisms having bioaccumulated toxins from the environment over their life spans), unbalanced river and lake ecosystems that can no longer support full biological diversity, deforestation from acid rain, and many other effects. These effects are, of course, specific to the various contaminants.

Contaminants may include organic and inorganic substances.

Some organic water pollutants are: Insecticides and herbicides, a huge range of organohalide and other chemicals, Bacteria, often is from sewage or livestock operations, Food processing waste, including pathogens, Tree and brush debris from logging operations, VOCs (Volatile organic compounds), such as industrial solvents, from improper storage, Petroleum Hydrocarbons including fuels (gasoline, diesel, jet fuels, and fuel oils) and lubricants (motor oil) from oil field operations, refineries, pipelines, retail service station's underground storage tanks, and transfer operations. Note: VOCs include gasoline-range hydrocarbons.

Some inorganic water pollutants include: Heavy metals including acid mine drainage, 
Acidity caused by industrial discharges (especially sulfur dioxide from power plants), Pre-production industrial raw resin pellets (an industrial pollutant), Chemical waste as industrial by products : Fertilizers, in runoff from agriculture including nitrates and phosphates. Silt in surface runoff from construction sites, logging, slash and burn practices or land clearing sites.

The sources of water pollution typically fall into one of two categories: point-source pollution and non-point-source pollution.

The term point-source pollution refers to pollutants discharged from one discrete location or point, such as an industry or municipal wastewater treatment plant. Pollutants discharged in this way might include, for example, fecal coliform bacteria and nutrients from sewage, and toxics such as heavy metals, or synthetic organic contaminants.

The term non-point-source pollution refers to pollutants that cannot be identified as coming from one discrete location or point. Examples are oil and grease that enter the water with runoff from urban streets, nitrogen from fertilizers and pesticides, and animal wastes that wash into surface waters from agricultural lands. Natural and unknown causes of pollutants also can impact water quality and may be related to human activities. For example, highway or housing construction may help precipitate the runoff of  natural pollution sources, such as sediment.

Potability of Water – Water for drinking

Regular testing is important to identify existing problems, ensure water is suitable for the intended use, ensure safe drinking water, and determine the effectiveness of a treatment system. The quality of a water source may change over time, even suddenly. Changes can go unnoticed as the water may look, smell, and taste the same.

Basic Water Potability Test packages include tests for coliform bacteria, nitrates, pH, sodium, chloride, fluoride, sulphate, iron, manganese, total dissolved solids, and hardness.
•    Coliform bacteria tests indicate the presence of microorganisms in the water that are potentially harmful to human health.
•    Nitrate is a common contaminant found mainly in groundwater. High nitrate concentrations can be particularly dangerous for babies under six months, since nitrate interferes with the ability of blood to carry oxygen.
•    Ions such as sodium, chloride, sulphate, iron, and manganese can impart objectionable taste or odour to water.
•    Excessive amounts of sulfate can have a laxative effect or cause gastrointestinal irritation.
•    Fluoride is an essential micro-nutrient, but excessive amounts can cause dental problems.
•    Total dissolved solids represent the amount of inorganic substances (i.e. sodium, chloride, sulphate) that are dissolved in the water. High total dissolved solids (TDS) can reduce the palatability of water.

Other tests may be appropriate if a particular contaminant is suspected in the water. For instance, groundwater sources are sometimes tested for arsenic, selenium, and uranium. Both surface and groundwater sources may also be tested for pesticide contamination. Domestic water supplies should be tested a minimum of once per year. Drinking water supplies obtained from shallow wells and surface water sources should be tested more frequently (i.e. seasonally), as they are more susceptible to contamination.

The following terms are commonly used as test parameters:

pH - represents the intensity of the acid or alkaline condition of a solution. A pH of 7 indicates neutral conditions on a scale of 0 (acidic) to 14 (alkaline).

Conductivity - measures the ability of water to conduct an electrical current, and is directly related to the total dissolved salts (ions) in the water.

Coliforms (Total) - bacteria found in faeces, soil, and vegetation, which is used to indicate the bacteriological quality of water. Coliforms indicate the possible presence of pathogenic bacteria and viruses.

Nitrate (NO3) - the most completely oxidized state of nitrogen found in water. High nitrate levels can occur naturally, but may indicate biological wastes in the water, or run-off from heavily fertilized fields. High nitrate levels reduce the ability of blood to transport oxygen to body tissues.

Total Hardness - mainly caused by the presence of calcium and magnesium in water, and is expressed as the equivalent quantity of calcium carbonate. Scale formation and excessive soap consumption are the main problems associated with hardness.

Total Dissolved Solids (TDS) - the total dissolved substances (i.e. salts and minerals) in water remaining after evaporating the water and weighing the residue.

Turbidity - represents the clarity of water. It is measured by the degree to which light is blocked because the water is muddy or cloudy.

Following are common questions and answers regarding the basic concepts of the bacterial indicator system used to monitor drinking water.

Q.  Are there bacteria in properly treated potable water?
A.  Yes.  Drinking water regulations require that potable waters, water for human consumption, be free from human-disease-causing bacteria and specific indicator bacteria that are indicative of the presence of these pathogens.  This does not mean that drinking water should be sterile.  Keep in mind that not all bacteria are harmful to humans.



Q.  What bacteria are harmful to the consumer?
A.  There are some bacteria that have a greater probability of causing disease in humans.  These bacteria are classified as pathogens.  Examples of bacterial pathogens and their related diseases are Salmonella typhi (typhoid fever), Shigella dysenteriae (dysentery), and Legionella pneumophilia (Legionnaire's Disease).
There are other bacteria that will cause disease in humans, but this usually occurs in situations where the individual has been immuno-compromised.  An immuno-compromised person can be very young or elderly, under antibiotic or chemotherapy treatment, undernourished, and so forth.  Bacteria that cause disease in these individuals are classified as opportunistic pathogens.  These bacteria take advantage of the compromised condition of the individual as an opportunity to develop disease symptoms.  However, under normal or healthy conditions, the individual's own body defenses would prevent the disease from developing.

Q.  How are bacteria indicative of contamination in drinking water?
A.  Originally, the bacterial species and bacterial groups that are of regulatory concern were considered to be strictly associated with feces.  However, it is now known that some of these bacteria can be isolated not only from human feces but also from the environment where no human fecal contamination has occurred.  There is no easy or inexpensive way to differentiate the source of these bacteria when isolated from a drinking water sample.  Therefore, erring on the side of safety, the regulations are based on the concept that the presence of these specific bacteria, regardless of their source, is indicative of fecal contamination from human or natural sources such as septic seepage, soils, and warm-blooded animals.  This may seem unfair to the water treatment plant operator, but if the plant is operated efficiently and the distribution system is maintained properly, the probability of introducing these bacteria into the distribution system drinking water is minimal.

Q.  What is coliform?
A.  By definition, the term coliform group includes those bacteria that are aerobic and facultatively anaerobic, gram-negative, nonsporeforming, rod-shaped bacteria capable of fermenting lactose with gas and acid production within 48 h ± 4 h at 35°C ± 0.5°C.

Q.  How does the technical definition of coliform group (previous answer) relate to a water treatment plant operator whose responsibility is the processing of water samples and interpretation of the results?
A.  Admittedly, there is more information given in the definition of coliform group than is required to understand the basic concepts of the coliform indicator system.  However, the descriptive terms used in the definition are necessary for classification of coliforms in relation to other bacteria and go beyond the intention of this handbook.  The characteristic used for diagnostic purposes that you should be familiar with is the fermentation or utilization of lactose that produces gas bubbles and acid in the media.
Specific examples on how to interpret diagnostic results when using different types of media follow in later chapters.  Also, depending on the technique used to analyze the water sample, such as multiple tube fermentation (MTF), presence-absence (PA), or membrane filter (MF), the definition for a coliform must be modified appropriately.  Therefore, it is not important to memorize this definition.  However, to understand why the definition must be modified when evaluating test results from the MTF technique versus the MF technique, it will be helpful to refer to this definition.

Q.  What are fecal coliforms?
A.  Fecal coliforms are defined in the same way as total coliforms except that fecal coliforms can ferment lactose at an elevated temperature when using standard media (44.5°C ± 0.2°C).  This increase in incubation temperature inhibits the growth and lactose fermentation of the other total coliforms, which ferment lactose optimally at 35°C ± 0.5°C.

Q.  Does the previous definition of fecal coliform apply to E. coli since it is a fecal coliform?
A.  Yes.  The only difference is in the standard media used to isolate E. coli.

Q.  Why is E. coli considered to be more specific for indicating potable water contamination than the other total and fecal coliforms?
A.  E. coli is more often directly associated with fecal contamination and disease outbreaks in potable waters than any of the other total or fecal coliforms.  Recent developments in the technology for isolating, recovering, and identifying E. coli have made a once difficult task relatively simple, affordable, and dependable.  Having a test that identifies the presence of a bacterium that is known to indicate the likelihood of fecal contamination gives the bacteriologist another technique for ensuring bacteriologically safe drinking water to the consumer.

Eutrophication is a process whereby water bodies, such as lakes, estuaries, or slow-moving streams receive excess nutrients that stimulate excessive plant growth (algae, periphyton attached algae, and nuisance plants weeds). This enhanced plant growth, often called an algal bloom, reduces dissolved oxygen in the water when dead plant material decomposes and can cause other organisms to die. Nutrients can come from many sources, such as fertilizers applied to agricultural fields, golf courses, and suburban lawns; deposition of nitrogen from the atmosphere; erosion of soil containing nutrients; and sewage treatment plant discharges. Water with a low concentration of dissolved oxygen is called hypoxic.

Eutrophication is caused by the decrease of an ecosystem with chemical nutrients, typically compounds containing nitrogen or phosphorus. It may occur on land or in the water. Eutrophication is frequently a result of nutrient pollution such as the release of sewage effluent into natural waters (rivers or coasts) although it may occur naturally in situations where nutrients accumulate (e.g. depositional environments) or where they flow into systems on an ephemeral basis (e.g. intermittent upwelling in coastal systems).

Eutrophication generally promotes excessive plant growth and decay, favors certain weedy species over others, and is likely to cause severe reductions in water quality. In aquatic environments, enhanced growth of choking aquatic vegetation or phytoplankton (that is, an algal bloom) disrupts normal functioning of the ecosystem, causing a variety of problems. Human society is impacted as well: eutrophication decreases the resource value of rivers, lakes, and estuaries such that recreation, fishing, hunting, and aesthetic enjoyment are hindered. Health-related problems can occur where eutrophic conditions interfere with drinking water treatment.
Although traditionally thought of as enrichment of aquatic systems by addition of fertilizers into lakes, bays, or other semi-enclosed waters (even slow-moving rivers), terrestrial ecosystems are subject to similarly adverse impacts. Increased content of nitrates in soil frequently leads to undesirable changes in vegetation composition and many plant species are endangered as a result of eutrophication in terrestric ecosystems, e.g. majority of orchid species in Europe. Ecosystems (like some meadows, forests and bogs that are characterized by low nutrient content and species-rich, slowly growing vegetation adapted to lower nutrient levels) are overgrown by faster growing and more competitive species-poor vegetation, like tall grasses, that can take advantage of unnaturally elevated nitrogen level and the area may be changed beyond recognition and vulnerable species may be lost. Eg. species-rich fens are overtaken by reed or reedgrass species, spectacular forest undergrowth affected by run-off from nearby fertilized field is turned into a thick nettle and bramble shrub.

Eutrophication was recognized as a pollution problem in European and North American lakes and reservoirs in the mid-20th century. Since then, it has become more widespread. Surveys showed that 54% of lakes in Asia are eutrophic; in Europe, 53%; in North America, 48%; in South America, 41%; and in Africa, 28%.

Concept of eutrophication

Eutrophication can be a natural process in lakes, as they fill in through geological time, though other lakes are known to demonstrate the reverse process, becoming less nutrient rich with time. Estuaries also tend to be naturally eutrophic because land-derived nutrients are concentrated where run-off enters the marine environment in a confined channel and mixing of relatively high nutrient fresh water with low nutrient marine water occurs.

Phosphorus is often regarded as the main culprit in cases of eutrophication in lakes subjected to point source pollution from sewage. The concentration of algae and the tropic state of lakes correspond well to phosphorus levels in water. Studies conducted in the Experimental Lakes Area in Ontario have shown a relationship between the addition of phosphorus and the rate of eutrophication. Humankind has increased the rate of phosphorus cycling on Earth by four times, mainly due to agricultural fertilizer production and application. Between 1950 and 1995, 600,000,000 tonnes of phosphorus were applied to Earth's surface, primarily on croplands. Control of point sources of phosphorus have resulted in rapid control of eutrophication, mainly due to policy changes.

Human activities can accelerate the rate at which nutrients enter ecosystems. Runoff
from agriculture and development, pollution from septic systems and sewers, and other human-related activities increase the flux of both inorganic nutrients and organic substances into terrestrial, aquatic, and coastal marine ecosystems (including coral reefs). Elevated atmospheric compounds of nitrogen can increase soil nitrogen availability.

Chemical forms of nitrogen are most often of concern with regard to eutrophication
because plants have high nitrogen requirements so that additions of nitrogen compounds stimulate plant growth (primary production). Nitrogen is not readily available in soil because N2, a gaseous form of nitrogen, is very stable and unavailable directly to higher plants. Terrestrial ecosystems rely on microbial nitrogen fixation to convert N2 into other physical forms (such as nitrates). However, there is a limit to how much nitrogen can be utilized. Ecosystems receiving more nitrogen than the plants require are called nitrogen-saturated. Saturated terrestrial ecosystems contribute both inorganic and organic nitrogen to freshwater, coastal, and marine eutrophication, where nitrogen is also typically a limiting nutrient. However, in marine environments, phosphorus may be limiting because it is leached from the soil at a much slower rate than nitrogen, which are highly insoluble.

Ecological effects
Adverse effects of eutrophication on lakes, reservoirs, rivers and coastal marine
waters
• Increased biomass of phytoplankton
• Toxic or inedible phytoplankton species
• Increases in blooms of gelatinous zooplankton
• Increased biomass of benthic and epiphytic algae
• Changes in macrophyte species composition and biomass
• Decreases in water transparency
• Taste, odor, and water treatment problems
• Dissolved oxygen depletion
• Increased incidences of fish kills
• Loss of desirable fish species
• Reductions in harvestable fish and shellfish
• Decreases in perceived aesthetic value of the water body

Many ecological effects can arise from stimulating primary production, but there are
three particularly troubling ecological impacts: decreased biodiversity, changes in species composition and dominance, and toxicity effects.

Decreased biodiversity

When an ecosystem experiences an increase in nutrients, primary producers reap the benefits first. In aquatic ecosystems, species such as algae experience a population increase (called an algal bloom). Algal blooms limit the sunlight available to bottom-dwelling organisms and cause wide swings in the amount of dissolved oxygen in the water.

Oxygen is required by all respiring plants and animals and it is replenished in daylight by photosynthesizing plants and algae. Under eutrophic conditions, dissolved oxygen greatly increases during the day, but is greatly reduced after dark by the respiring algae and by microorganisms that feed on the increasing mass of dead algae. When dissolved oxygen levels decline to hypoxic levels, fish and other marine animals suffocate. As a result, creatures such as fish, shrimp, and especially immobile bottom dwellers die off. In extreme cases, anaerobic conditions ensue, promoting growth of bacteria such as Clostridium botulinum that produces toxins deadly to birds and mammals. Zones where this occurs are known as dead zones.

Sources of high nutrient runoff

Characteristics of point and nonpoint sources of chemical inputs

Point sources

• Wastewater effluent (municipal and industrial)
• Runoff and leachate from waste disposal systems
• Runoff and infiltration from animal feedlots
• Runoff from mines, oil fields, unsewered industrial sites
• Overflows of combined storm and sanitary sewers
• Runoff from construction sites >20,000 m²


Nonpoint Sources

• Runoff from agriculture/irrigation
• Runoff from pasture and range
• Urban runoff from unsewered areas
• Septic tank leachate
• Runoff from construction sites <20,000 m²
• Runoff from abandoned mines
• Atmospheric deposition over a water surface
• Other land activities generating contaminants

Point sources are directly attributable to one influence. In point sources the nutrient waste travels directly from source to water. For example, factories that have waste discharge pipes directly leading into a water body would be classified as a point source. Point sources are relatively easy to regulate.

Nonpoint source pollution (also known as 'diffuse' or 'runoff' pollution) is that which comes from ill-defined and diffuse sources. Nonpoint sources are difficult to regulate and usually vary spatially and temporally (with season, precipitation, and other irregular events). It has been shown that nitrogen transport is correlated with various indices of human activity in watersheds, including the amount of development. Agriculture and development are activities that contribute most to nutrient loading.

There are three reasons that nonpoint sources are especially troublesome:
• Soil retention
• Runoff to surface water and leaching to groundwater
• Atmospheric deposition

Prevention and reversal

Eutrophication poses a problem not only to ecosystems, but to humans as well. Reducing eutrophication should be a key concern when considering future policy, and a sustainable solution for everyone, including farmers and ranchers, seems feasible. While eutrophication does pose problems, humans should be aware that natural runoff (which causes algal blooms in the wild) is common in ecosystems and should thus not reverse nutrient concentrations beyond normal levels.

Cleanup measures have been mostly, but not completely, successful. Finish phosphorus removal measures started in the mid-1970s and have targeted rivers and lakes polluted by industrial and municipal discharges. These efforts have had a 90% removal efficiency. Still, some targeted point sources did not show a decrease in runoff despite reduction efforts.

Impact of farming
Farming is what makes possible the production of food surpluses and settled living. It also brings about big changes in the relationships between living things and in their habitats. Farming - especially modern, intensive farming can damage the environment in many different ways.

Effect of fertilizers
Fertilisers containing plant nutrients are sprayed onto fields to make plants grow faster and boost crop yields. When it rains the nutrients may get washed down from the fields and into rivers and lakes (this is called run-off). The result is eutrophication – which can kill almost everything living in the aquatic environment. It works like this:
Effect of pesticides
Pesticides are chemicals used to kill insects, weeds and microorganisms that might damage crops. However, pesticides damage other organisms apart from those they are intended to kill - for example, depriving insect-eating birds of food. Pesticides can also enter local food chains. Organisms that ingest them cannot break them down, so they persist in their bodies. (Substances that cannot be broken down are called persistent substances: the pesticide DDT is an example.) The pesticides may then build up at ever-higher levels until they become toxic to much larger organisms.

Other impacts of farming
Agriculture can impact on the environment in many other ways. For example:
• farming takes up land, reducing habitats and wildlife
• monocultures (large amounts of one type of food) provide lots of food for
pests as well as humans
• irrigation (watering of crops) may take too much water from rivers, depriving
downstream habitats of water
• clearing land for farming may result in soil erosion, damaging ecosystems
and leaving land barren
• Intensive livestock farming produces huge amount of faeces, which may
pollute waterways
 
Rainwater Harvesting is the collection and storage of rain from roofs or from a surface catchment for future use. The water is generally stored in rainwater tanks or directed into mechanisms which recharge groundwater. This is appropriate in many parts of the world, such as western Britain, China, Brazil, Thailand, Sri Lanka, Germany, Australia and India, where there is enough rain for collection and conventional water resources either do not exist or are at risk of being over-used to supply a large population. Rainwater harvesting can provide lifeline water for human consumption, reduce water bills and the need to build reservoirs which may require the use of valuable land.

Traditionally, rainwater harvesting has been practised in arid and semi-arid areas, and has provided drinking water, domestic water, water for livestock, water for small irrigation and a way to replenish ground water levels. This method may have been used extensively by the Indus Valley Civilization.

Currently in China and Brazil, rooftop rainwater harvesting is being practised for use for all the above purposes. Gansu province in China and semi-arid north east Brazil have the largest rooftop rainwater harvesting projects ongoing.

Rainwater harvesting in urban areas can have manifold reasons. To provide supplemental water for the city's requirement, to increase soil moisture levels for urban greenery, to increase the ground water table through artificial recharge, to mitigate urban flooding and to improve the quality of groundwater are some of the reasons why rainwater harvesting can be adopted in cities. In urban areas of the developed world, at a household level, harvested rainwater can be used for flushing toilets and washing laundry. Indeed in hard water areas it is superior to mains water for this. It can also be used for showering or bathing. It may require treatment prior to use for drinking.

Two residences in the city of Toronto, Canada, use treated harvested rainwater for drinking water, and reuse water (i.e. treated wastewater) for all other household water applications including toilet flushing, bathing, showers, laundry, and garden irrigation (Toronto Healthy House).
In New Zealand, many houses away from the larger towns and cities routinely rely on rainwater collected from roofs as the only source of water for all household activities.

RAIN WATER HARVESTING AND ARTIFICIAL RECHARGE TO GROUND WATER

WHAT IS RAIN WATER HARVESTING :
It is the principle of collecting and using precipitation from a catchments surface. An old technology is gaining popularity in a new way. Rain water harvesting is enjoying a renaissance of sorts in the world, but it traces its history to biblical times. Extensive rain water harvesting apparatus existed 4000 years ago in the Palestine and Greece. In ancient Rome, residences were built with individual cisterns and paved courtyards to capture rain water to augment water from city's aqueducts. As early as the third millennium BC, farming communities in Baluchistan and Kutch impounded rain water and used it for irrigation dams.

ARTIFICAL RECHARGE TO GROUND WATER :
Artificial recharge to ground water is a process by which the ground water reservoir is augmented at a rate exceeding that obtaining under natural conditions or replenishment. Any man-made scheme or facility that adds water to an aquifer may be considered to be an artificial recharge system.

WHY RAIN WATER HARVESTING :
Rain water harvesting is essential because :-
Surface water is inadequate to meet our demand and we have to depend on ground water.
Due to rapid urbanization, infiltration of rain water into the sub-soil has decreased drastically and recharging of ground water has diminished.
As you read this guide, seriously consider conserving water by harvesting and managing this natural resource by artificially recharging the system. The examples covering several dozen installations successfully operating in India constructed and maintained by CGWB, provide an excellent snapshot of current systems.

RAIN WATER HARVESTING TECHNIQUES :
There are two main techniques of rain water harvestings. Storage of rainwater on surface for future use. Recharge to ground water.

The storage of rain water on surface is a traditional techniques and structures used were underground tanks, ponds, check dams, weirs etc. Recharge to ground water is a new concept of rain water harvesting and the structures generally used are:-

Pits :- Recharge pits are constructed for recharging the shallow aquifer. These are constructed 1 to 2 m, wide and to 3 m. deep which are back filled with boulders, gravels, coarse sand.

Trenches:- These are constructed when the permeable stram is available at shallow depth. Trench may be 0.5 to 1 m. wide, 1 to 1.5m. deep and 10 to 20 m. long depending up availability of water. These are back filled with filter. materials.

Dug wells:- Existing dug wells may be utilised as recharge structure and water should pass through filter media before putting into dug well.
Hand pumps :- The existing hand pumps may be used for recharging the shallow/deep aquifers, if the availability of water is limited. Water should pass through filter media before diverting it into hand pumps.

Recharge wells :- Recharge wells of 100 to 300 mm. diameter are generally constructed for recharging the deeper aquifers and water is passed through filter media to avoid choking of recharge wells.

Recharge Shafts :- For recharging the shallow aquifer which are located below clayey surface, recharge shafts of 0.5 to 3 m. diameter and 10 to 15 m. deep are constructed and back filled with boulders, gravels & coarse sand.

Lateral shafts with bore wells :- For recharging the upper as well as deeper aquifers lateral shafts of 1.5 to 2 m. wide & 10 to 30 m. long depending upon availability of water with one or two bore wells are constructed. The lateral shafts is back filled with boulders, gravels & coarse sand.

Spreading techniques :- When permeable strata starts from top then this technique is used. Spread the water in streams/Nalas by making check dams, nala bunds, cement plugs, gabion structures or a percolation pond may be constructed.

HARVESTING RAINWATER HARNESSING LIFE : A NOBLE GOAL - A COMMON RESPONSIBILITY

Ground water exploitation is inevitable is Urban areas. But the groundwater potential is getting reduced due to urbanisation resulting in over exploitation. Hence, a strategy to implement the groundwater recharge, in a major way need to be launched with concerted efforts by various Governmental and Non-Governmental Agencies and Public at large to build up the water table and make the groundwater resource, a reliable and sustainable source for supplementing water supply needs of the urban dwellers.

Recharge of groundwater through storm run off and roof top water collection, diversion and collection of run off into dry tanks, play grounds, parks and other vacant places are to be implemented by Special Village Panchayats/ Municipalities /Municipal Corporations and other Government Establishments with special efforts.

The Special Village Panchayats /Municipalities/Municipal Corporations will help the citizens and builders to adopt suitable recharge method in one's own house or building through demonstration and offering subsidies for materials and incentives, if possible.

ATTRIBUTES OF GROUNDWATER :
o    There is more ground water than surface water
o    Ground water is less expensive and economic resource.
o    Ground water is sustainable and reliable source of water supply.
o    Ground water is relatively less vulnerable to pollution
o    Ground water is usually of high bacteriological purity.
o    Ground water is free of pathogenic organisms.
o    Ground water needs little treatment before use.
o    Ground water has no turbidity and colour.
o    Ground water has distinct health advantage as art alternative for lower sanitary quality surface water.
o    Ground water is usually universally available.
o    Ground water resource can be instantly developed and used.
o    There is no conveyance losses in ground water based supplies.
o    Ground water has low vulnerability to drought.
o    Ground water is key to life in arid and semi-arid regions.
o    Ground water is source of dry weather flow in rivers and streams.


Module IV - Frequently Asked Questions and Toxic effect of air pollution

What is Ozone? 

Ozone is an odourless, colourless gas at ambient concentrations and is one of the main components of smog. 

What are the sources of ozone? 

Ground-level ozone is not released straight into the atmosphere. It comes from photo-chemical reactions between nitrogen oxide (NOx) and volatile organic carbons in the presence of sunlight. From May to September, between noon and early evening are when high levels of ozone usually occur. 

How does ozone affect people and the environment? 

O3 causes irritation to the respiratory tract and to eyes. Contact with high levels of ozone can lead to chest tightness, coughing and wheezing. When exposed to ozone people that have respiratory or heart problems are at a higher risk. Ozone has been connected to increased hospital admissions and premature death. Ozone also has an impact on agriculture and crops.
What is Nitrogen Dioxide?
Nitrogen Dioxide is gas that is reddish-brown in colour and has a strong and irritating smell. In the air, nitrogen dioxide converts to form gaseous nitric acid and toxic organic nitrates. NO2 also plays a large part in atmospheric reactions that create ground level ozone, a main part in the makeup of smog. It is also a predecessor to nitrates which add to increased respirable particle levels in the atmosphere. 

What are the sources of Nitrogen Dioxide? 

All combustion in the air (ie car exhaust) creates oxides of nitrogen (Nox), of which NO2 is a major product. Natural sources of Nox include lightning and the aerobic activity of soil bacteria. However, these natural sources of emission are minor compared to those created by human activity. 

How does Nitrogen Dioxide affect people and the environment? 

Nitrogen dioxide can aggravate the lungs and reduce resistance to respiratory infection. For people with asthma and bronchitis an increase in sensitivity occurs. NO2 chemically changes into nitric acid and, when deposited contributes to lake acidification. Once chemically changed to nitric acid, nitrogen dioxide can corrode metals, fade fabrics, and degrade rubber. It can damage trees and crops, resulting in great losses. 

What are suspended particles? 

Suspended particles in the atmosphere are comprised of either solid particles or fine liquid droplets. Included in this group are: aerosols, smoke, fumes, dust, fly ash and pollen. The exact make up varies with both place and season. Particles in the atmosphere have been categorized based on size mostly because of the different health affect from particles of different diameters.
Particles with diameters of less than 100 microns (millionths of a metre) are classified as total suspended particles (TSP). In order to visualize how small a micron is, one micron is approximately the size of a single bacteria. Particles that are less than 10 microns and 2.5 microns are defined as inhalable particles (PM10) and respirable particles (PM2.5), respectively. The tinier the particle size, the further that particle will penetrate into the lungs. 

What are the sources of suspended particles? 

The bulk of the particle emissions from human activity can be categorized as TSP (total suspended particles).
Particles come from both natural and man made sources. Some of the natural sources include: windblown soil and mineral particles, volcanic ash, sea salt spray, and biological materials such as pollen, spores, bacteria and smoke from forest fires. The man-made sources result in both coarse and fine particles. Coarse particle matter comes from wind blown dust from agricultural soil, roads and construction sites. Smaller particles are created by the combustion of fossil fuel, residential heating and other sources as well. They can be released directly from a given source or formed in the atmosphere through the transformation of gaseous emissions. The composition of the particles varies with place, season, meteorology and daily weather. 

How do suspended particles affect people and the environment? 

The greatest effect on health comes from particles 10 microns or less in diameter PM10. Particles in this range can irritate bronchitis, asthma and other respiratory diseases. In some cases these small particles have been connected to greater hospital admissions and premature death. Those people that are most susceptible to the effects of particles include: those with asthma, cardiovascular or lung disease, as well as children and the elderly. Particles also cause corrosion, soiling damage to vegetation and visibility reduction.

What are Total Reduced Sulphur compounds? 

Total Reduced Sulphur compounds create strong odours reminiscent of cabbage or rotten eggs. 

What are the sources of TRS? 

Industrial sources such as the steel industry, pulp and paper mills, refineries and sewage treatment facilities are all contributors. Natural sources of TRS include swamps, bogs and marshes. 

What effect does TRS have on people and the environment? 

Usually TRS compounds are not considered to be a health hazard. TRS compounds are one of the main causes of odours. 

What is sulphur dioxide? 

Sulphur dioxide is a colourless gas that smells like burnt matches. It can be oxidized to form sulphur trioxide. Which in the company of water vapour is easily changed to sulphuric acid mist. SO2 can be oxidized to form acid aeorsols. Sulphur dioxide is the predecessor to sulphates, which are one of the main components of respirable particles in the atmosphere. 

What are the sources of sulphur dioxide? 

Industrial sources of this gas include iron and steel mills, petroleum refineries and pulp and paper mills. Small sources include residential, commercial and industrial space heating. 

What are the effects of Sulphur Dioxide on people and the environment? 

Being exposed to high levels of SO2 can cause breathing problems, respiratory illness, changes in the lung's defences, and worsening respiratory and cardiovascular disease. People that are most sensitive to sulphur dioxide are those with asthma or chronic lung or heart disease. It also causes damage to trees and crops. Sulphur Dioxide, along with Nitrogen Oxides, are the precursors of acid rain. This adds to the acidification of lakes and streams, accelerated corrosion of buildings and a reduction in visibility. Sulphur Dioxide also leads to the formation of microscopic acid aerosols, which has a major impact on health as well as contributing to climate change. 

What is Carbon Monoxide? 

CO is a colourless, odourless and tasteless but poisonous gas produced primarily by incomplete burning of fossil fuels. 

What are the sources of CO? 

The transportation sector accounts for 65 per cent of all CO emissions from human activity in Ontario as seen in the table and diagram below. A large part of the remainder comes from primary metal producers (24 per cent) and from fuel combustion in space heating and industrial processes (6 per cent).

What are the effects of CO? 

CO enters the blood stream and reduces oxygen delivery to the organs and tissues. People with heart disease are particularly sensitive. Exposure to high levels is linked with impairment of vision, work capacity, learning ability and performance of difficult tasks.

What are toxic air pollutants?

Toxic air pollutants, also known as hazardous air pollutants, are those pollutants that are known or suspected to cause cancer or other serious health effects, such as reproductive effects or birth defects, or adverse environmental effects. EPA is working with state, local, and tribal governments to reduce air toxics releases of 188 pollutants to the environment. Examples of toxic air pollutants include benzene, which is found in gasoline; perchlorethlyene, which is emitted from some dry cleaning facilities; and methylene chloride, which is used as a solvent and paint stripper by a number of industries. Examples of other listed air toxics include dioxin, asbestos, toluene, and metals such as cadmium, mercury, chromium, and lead compounds. 

What are the health and environmental effects of toxic air pollutants?

People exposed to toxic air pollutants at sufficient concentrations and durations may have an increased chance of getting cancer or experiencing other serious health effects. These health effects can include damage to the immune system, as well as neurological, reproductive (e.g., reduced fertility), developmental, respiratory and other health problems. In addition to exposure from breathing air toxics, some toxic air pollutants such as mercury can deposit onto soils or surface waters, where they are taken up by plants and ingested by animals and are eventually magnified up through the food chain. Like humans, animals may experience health problems if exposed to sufficient quantities of air toxics over time. 

Where do toxic air pollutants come from?

Most air toxics originate from human-made sources, including mobile sources (e.g., cars, trucks, buses) and stationary sources (e.g., factories, refineries, power plants), as well as indoor sources (e.g., some building materials and cleaning solvents). Some air toxics are also released from natural sources such as volcanic eruptions and forest fires. 

How are people exposed to air toxics?

People are exposed to toxic air pollutants in many ways that can pose health risks, such as by:
Breathing contaminated air.
Eating contaminated food products, such as fish from contaminated waters; meat, milk, or eggs from animals that fed on contaminated plants; and fruits and vegetables grown in contaminated soil on which air toxics have been deposited.
Drinking water contaminated by toxic air pollutants.
Ingesting contaminated soil. Young children are especially vulnerable because they often ingest soil from their hands or from objects they place in their mouths.
Touching (making skin contact with) contaminated soil, dust, or water (for example, during recreational use of contaminated water bodies).
Once toxic air pollutants enter the body, some persistent toxic air pollutants accumulate in body tissues. Predators typically accumulate even greater pollutant concentrations than their contaminated prey. As a result, people and other animals at the top of the food chain who eat contaminated fish or meat are exposed to concentrations that are much higher than the concentrations in the water, air, or soil.

Module IV - Smog - photochemical smog

Smog
Smog is a kind of air pollution; the word "smog" is a portmanteau [A portmanteau word is a combination of two or more words and their definitions, into one new word.] of smoke and fog. Classic smog results from large amounts of coal burning in an area and is caused by a mixture of smoke and sulphur dioxide.
The term "smog" was first coined by Dr. Henry Antoine Des Voeux in his 1905 paper, “Fog and Smoke,” for a meeting of the Public Health Congress. The 26 July 1905 edition of the London newspaper Daily Graphic quoted Des Voeux, “It required no science to see that there was something produced in great cities which was not found in the country, and that was smoky fog, or what was known as ‘smog.’” The following day the newspaper stated that “Dr. Des Voeux did a public service in coining a new word for the London fog.”
Smog is a problem in a number of cities and continues to harm human health. Ground-level ozone, Sulfur dioxide, Nitrogen dioxide Carbon monoxide are especially harmful for senior citizens, children, and people with heart and lung conditions such as emphysema, bronchitis, and asthma. It can inflame breathing passages, decreasing the lungs' working capacity, and causing shortness of breath, pain when inhaling deeply, wheezing, and coughing. It can cause eye and nose irritation and it dries out the protective membranes of the nose and throat and interferes with the body's ability to fight infection, increasing susceptibility to illness. Hospital admissions and respiratory deaths often increase during periods when ozone levels are high.
In the 1950s a new type of smog, known as photochemical smog, was first described. This is a noxious mixture of air pollutants including the following:
nitrogen oxides, such as nitrogen dioxide, tropospheric ozone, volatile organic compounds (VOCs), peroxyacyl nitrates (PAN), aldehydes (R'O)
All of these chemicals are usually highly reactive and oxidizing. Due to this fact, photochemical smog is considered to be a problem of modern industrialization.
Photochemical smog is a concern in most major urban centres but, because it travels with the wind, it can affect sparsely populated areas as well. Smog is caused by a reaction between sunlight and emissions mainly from human activity. Photochemical smog is the chemical reaction of sunlight, nitrogen oxides (NOx) and volatile organic compounds (VOC's) in the atmosphere, which leaves airborne particles (called particulate matter) and ground-level ozone. Nitrogen oxides are released in the exhaust of fossil fuel-burning engines in cars, trucks, coal power plants, and industrial manufacturing factories. VOC's are vapors released from anthropogenic (man-made) sources such as gasoline, paints, solvents, pesticides, and biogenic sources, such as pine and citrus tree emissions.

Photochemical Smog
Photochemical smog is a type of air pollution produced when sunlight acts upon motor vehicle exhaust gases to form harmful substances such as ozone (O3), aldehydes and peroxyacetylnitrate (PAN) and mixed with particulate matters. Ozone causes breathing difficulties, headaches, fatigue and can aggravate respiratory problems. The peroxyacetylnitrate (CH3CO-OO-NO2) in photochemical smog can irritate the eyes, causing them to water and sting.

Ozone Production
Motor vehicles produce exhaust gases containing oxides of nitrogen such as nitrogen dioxide (NO2) and nitric oxide (NO).
At the high temperatures of the car's combustion chamber (cylinder), nitrogen and oxygen from the air react to form nitric oxide (NO):
N2(g) + O2(g) -----> 2NO(g)
Some of the nitric oxide (NO) reacts with oxygen to form nitrogen dioxide (NO2):
2NO(g) + O2(g) -----> 2NO2(g)
The mixture of nitric oxide (NO) and nitrogen dioxide (NO2) is sometimes referred to as NOx.
When the nitrogen dioxide (NO2) concentration is well above clean air levels and there is plenty of sunlight, then an oxygen atom splits off from the nitrogen dioxide molecule:
NO2(g)    sunlight---------->    NO(g)    +    O(g)
This oxygen atom (O) can react with oxygen molecules (O2) in the air to form ozone (O3): O + O2 -----> O3
Nitric oxide can remove ozone by reacting with it to form nitrogen dioxide (NO2) and oxygen (O2): NO(g) + O3(g) -----> NO2(g) + O2(g)
When the ratio of NO2 to NO is greater than 3, the formation of ozone is the dominant reaction. If the ratio is less than 0.3, then the nitric oxide reaction destroys the ozone at about the same rate as it is formed, keeping the ozone concentration below harmful levels.
The reaction of hydrocarbons (unburnt petrol) with nitric oxide and oxygen produce nitrogen dioxide also in the presence of sunlight, increasing the ratio of nitrogen dioxide to nitric oxide.

Peroxyacetylnitrate (PAN) Production
Nitrogen dioxide (NO2), oxygen (O2) and hydrocarbons (unburnt petrol) react in the presence of sunlight to produce peroxyacetylnitrate (CH3CO-OO-NO2):
NO2(g) + O2(g) + hydrocarbons + sunlight----------> CH3CO-OO-NO2(g)

1. It can cause headaches, eye, nose and throat irritations. It may cause the lung function impaired, coughing and wheezing. 2. It can cause rubbers and fabrics to deteriorate. 3. It can damage plants, leading to the loss of crops.

Catalytic Converters
Catalytic converters on motor vehicle exhausts are a way of trying to reduce the carbon monoxide and nitrogen oxide emissions.
The catalyst used is either platinum or a combination of platinum and rhodium.
The platinum catalyses the reaction of unburnt hydrocarbon (such as pentane) and oxygen (O2) to produce carbon dioxide (CO2) and water vapour (H2O):
C5H12(pentane)+8O2  (platinum catalyst)------------------->5CO2+    6H2O
The rhodium catalyses the reaction of carbon monoxide (CO) and nitric oxide (NO) to form carbon dioxide (CO2) and nitrogen gas (N2):
2CO + 2NO    rhodium catalyst------------------->2CO2 + N2
The reduction of nitric oxide (NO) to nitrogen gas (N2) must proceed more quickly than the oxidation of carbon monoxide (CO) to carbon dioxide (CO2) or else all the carbon monoxide will be oxidised to carbon dioxide before it can be used to reduce the nitric oxide.
Motor vehicles can only use catalytic converters if they use unleaded petrol since the lead in petrol renders the catalyst inactive.
In urban areas, air pollutants contribute to the formation of smog.  There are two types of smog.  The first to be identified, with reports dating back to the 17th century, was sulphurous smog.  This smog is characterized by high concentrations of sulphur compounds (i.e., SO2 and sulphates), resulting from the combustion of coal and high-sulphur content fuels.

Module IV - Global Warming - Greenhouse gases


Global warming refers to the increase in the average temperature of the Earth's near-surface air and oceans in recent decades and its projected continuation.
The measured global average air temperature near the Earth's surface rose 0.74 ± 0.18 °C (1.33 ± 0.32 °F) during the last 100 years. The Intergovernmental Panel on Climate Change (IPCC) concludes, "most of the observed increase in globally averaged temperatures since the mid-20th century is very likely due to the observed increase in anthropogenic greenhouse gas concentrations" via the greenhouse effect. Natural phenomena such as solar variation combined with volcanoes probably had a small warming effect from pre-industrial times to 1950 and a small cooling effect from 1950 onward. These basic conclusions have been endorsed by at least 30 scientific societies and academies of science, including all of the national academies of science of the major industrialized countries. However, a few individual scientists disagree with some of the main conclusions of the IPCC.
Climate models referenced by the IPCC project that global surface temperatures are likely to increase by 1.1 to 6.4 °C (2.0 to 11.5 °F) between 1990 and 2100. The range of values results from the use of differing scenarios of future greenhouse gas emissions as well as models with differing climate sensitivity. Although most studies focus on the period up to 2100, warming and sea level rise are expected to continue for more than a millennium even if greenhouse gas levels are stabilized. This reflects the large heat capacity of the oceans.
An increase in global temperatures is expected to cause other changes, including sea level rise, increased intensity of extreme weather events, and changes in the amount and pattern of precipitation. Other effects of global warming include changes in agricultural yields, glacier retreat, species extinctions and increases in the ranges of disease vectors.
Remaining scientific uncertainties include the amount of warming expected in the future, and how warming and related changes will vary from region to region around the globe. There is ongoing political and public debate worldwide regarding what, if any, action should be taken to reduce or reverse future warming or to adapt to its expected consequences. Most national governments have signed and ratified the Kyoto Protocol, aimed at reducing greenhouse gas emissions.
Causes : Green House Gases and Green House Effects, Solar Variation.

Greenhouse gases
Greenhouse gases are components of the atmosphere that contribute to the greenhouse effect. Some greenhouse gases occur naturally in the atmosphere, while others result from human activities such as burning of fossil fuels such as coal. Greenhouse gases include water vapor, carbon dioxide, methane, nitrous oxide, and ozone.
When sunlight reaches the surface of the Earth, some of it is absorbed and warms the surface. Because the Earth's surface is much cooler than the sun, it radiates energy at much longer wavelengths than does the sun. The atmosphere absorbs these longer wavelengths more effectively than it does the shorter wavelengths from the sun. The absorption of this longwave radiant energy warms the atmosphere; the atmosphere also is warmed by transfer of sensible and latent heat from the surface. Greenhouse gases also emit longwave radiation both upward to space and downward to the surface. The downward part of this longwave radiation emitted by the atmosphere is the "greenhouse effect." The term is a misnomer, as this process is not the mechanism that warms greenhouses.
The major greenhouse gases are water vapor, which causes about 36-70% of the greenhouse effect on Earth (not including clouds); carbon dioxide, which causes 9-26%; methane, which causes 4-9%, and ozone, which causes 3-7%. It is not possible to state that a certain gas causes a certain percentage of the greenhouse effect, because the influences of the various gases are not additive. Other greenhouse gases include, but are not limited to, nitrous oxide, sulfur hexafluoride, hydrofluorocarbons, perfluorocarbons and chlorofluorocarbons. The major atmospheric constituents (nitrogen, N2 and oxygen, O2) are not greenhouse gases. This is because homonuclear diatomic molecules such as N2 and O2 neither absorb nor emit infrared radiation, as there is no net change in the dipole moment of these molecules when they vibrate. Molecular vibrations occur at energies that are of the same magnitude as the energy of the photons on infrared light. Heteronuclear diatomics such as CO or HCl absorb IR; however, these molecules are short-lived in the atmosphere owing to their reactivity and solubility. As a consequence they do not contribute significantly to the greenhouse effect.
Late 19th century scientists experimentally discovered that N2 and O2 did not absorb infrared radiation (called, at that time, "dark radiation") and that CO2 and many other gases did absorb such radiation. It was recognized in the early 20th century that the known major greenhouse gases in the atmosphere caused the earth's temperature to be higher than it would have been without the greenhouse gases.

Anthropogenic greenhouse gases
The concentrations of several greenhouse gases have increased over time. Human activity increases the greenhouse effect primarily through release of carbon dioxide, but human influences on other greenhouse gases can also be important. Some of the main sources of greenhouse gases due to human activity include: burning of fossil fuels and deforestation leading to higher carbon dioxide concentrations; livestock and paddy rice farming, land use and wetland changes, pipeline losses, and covered vented landfill emissions leading to higher methane atmospheric concentrations. According to the Food and Agriculture Organization of the United Nations, the livestock industry is responsible for 18 percent of greenhouse gas emissions measured in CO2 equivalent, a higher share than transportation. Many of the newer style fully vented septic systems that enhance and target the fermentation process also are major sources of atmospheric methane;
use of chlorofluorocarbons (CFCs) in refrigeration systems, and use of CFCs and halons in fire suppression systems and manufacturing processes.
Agricultural activities, including the use of fertilizers, that lead to higher nitrous oxide concentrations.
The seven sources of CO2 from fossil fuel combustion are (with percentage contributions for 2000-2004): Solid fuels (e.g. coal): 35% Liquid fuels (e.g. gasoline): 36% Gaseous fuels (e.g. natural gas): 20% Flaring gas industrially and at wells: <1% Cement production: 3% Non-fuel hydrocarbons: <1%  The "international bunkers" of shipping and air transport not included in national inventories: 4%
Greenhouse gas emissions from industry, transportation and agriculture are very likely the main cause of recently observed global warming. Major sources of an individual's GHG include home heating and cooling, electricity consumption, and transportation. Corresponding conservation measures are improving home building insulation, cellular shades, compact fluorescent lamps and choosing high miles per gallon vehicles.
Carbon dioxide, methane, nitrous oxide and three groups of fluorinated gases (sulfur hexafluoride, HFCs, and PFCs) are the major greenhouse gases and the subject of the Kyoto Protocol, which entered into force in 2005.
CFCs, although greenhouse gases, are regulated by the Montreal Protocol, which was motivated by CFCs' contribution to ozone depletion rather than by their contribution to global warming. Note that ozone depletion has only a minor role in greenhouse warming though the two processes often are confused in the popular media.


Module IV - Ozone depletion

Ozone depletion & Ozone Hole
Ozone depletion describes two distinct, but related observations: a slow, steady decline of about 4 percent per decade in the total amount of ozone in Earth's stratosphere since around 1980; and a much larger, but seasonal, decrease in stratospheric ozone over Earth's polar regions during the same period. The latter phenomenon is commonly referred to as the ozone hole.
In addition to this well-known stratospheric ozone depletion, there are also tropospheric ozone depletion events, which occur near the surface in polar regions during spring.
The detailed mechanism by which the polar ozone holes form is different from that for the mid-latitude thinning, but the most important process in both trends is catalytic destruction of ozone by atomic chlorine and bromine. The main source of these halogen atoms in the stratosphere is photodissociation of chlorofluorocarbon (CFC) compounds, commonly called freons, and of bromofluorocarbon compounds known as halons. These compounds are transported into the stratosphere after being emitted at the surface. Both ozone depletion mechanisms strengthened as emissions of CFCs and halons increased.
CFCs, halons and other contributory substances are commonly referred to as ozone-depleting substances (ODS). Since the ozone layer prevents most harmful UVB wavelengths (270–315 nm) of ultraviolet light (UV light) from passing through the Earth's atmosphere, observed and projected decreases in ozone have generated worldwide concern leading to adoption of the Montreal Protocol banning the production of CFCs and halons as well as related ozone depleting chemicals such as carbon tetrachloride and trichloroethane. It is suspected that a variety of biological consequences such as increases in skin cancer, damage to plants, and reduction of plankton populations in the ocean's photic zone may result from the increased UV exposure due to ozone depletion.

Three forms (or allotropes) of oxygen are involved in the ozone-oxygen cycle: Oxygen atoms (O or atomic oxygen), oxygen gas (O2 or diatomic oxygen), and ozone gas (O3 or triatomic oxygen). Ozone is formed in the stratosphere when oxygen molecules photodissociate after absorbing an ultraviolet photon whose wavelength is shorter than 240 nm. This produces two oxygen atoms. The atomic oxygen then combines with O2 to create O3. Ozone molecules absorb UV light between 310 and 200 nm, following which ozone splits into a molecule of O2 and an oxygen atom. The oxygen atom then joins up with an oxygen molecule to regenerate ozone. This is a continuing process which terminates when an oxygen atom "recombines" with an ozone molecule to make two O2 molecules: O + O3 → 2 O2
The overall amount of ozone in the stratosphere is determined by a balance between photochemical production and recombination.
Ozone can be destroyed by a number of free radical catalysts, the most important of which are the hydroxyl radical (OH•), the nitric oxide radical (NO•) and atomic chlorine (Cl•) and bromine (Br•). All of these have both natural and anthropogenic (manmade) sources; at the present time, most of the OH• and NO• in the stratosphere is of natural origin, but human activity has dramatically increased the chlorine and bromine. These elements are found in certain stable organic compounds, especially chlorofluorocarbons (CFCs), which may find their way to the stratosphere without being destroyed in the troposphere due to their low reactivity. Once in the stratosphere, the Cl and Br atoms are liberated from the parent compounds by the action of ultraviolet light, e.g. ('h' is Planck's constant, 'ν' is frequency of electromagnetic radiation)
CFCl3 + hν → CFCl2 + Cl
The Cl and Br atoms can then destroy ozone molecules through a variety of catalytic cycles. In the simplest example of such a cycle, a chlorine atom reacts with an ozone molecule, taking an oxygen atom with it (forming ClO) and leaving a normal oxygen molecule. A free oxygen atom then takes away the oxygen from the ClO, and the final result is an oxygen molecule and a chlorine atom, which then reinitiates the cycle. The chemical shorthand for these gas-phase reactions is:
Cl + O3 → ClO + O2
ClO + O → Cl + O2
The net reaction is: O3 + O → 2 O2, the "recombination" reaction given above.
The overall effect is to increase the rate of recombination, leading to an overall decrease in the amount of ozone. For this particular mechanism to operate there must be a source of O atoms, which is primarily the photodissociation of O3; thus this mechanism is only important in the upper stratosphere where such atoms are abundant. More complicated mechanisms have been discovered that lead to ozone destruction in the lower stratosphere as well.
A single chlorine atom would keep on destroying ozone for up to two years (the time scale for transport back down to the troposphere) were it not for reactions that remove them from this cycle by forming reservoir species such as hydrogen chloride (HCl) and chlorine nitrate (ClONO2). On a per atom basis, bromine is even more efficient than chlorine at destroying ozone, but there is much less bromine in the atmosphere at present. As a result, both chlorine and bromine contribute significantly to the overall ozone depletion. Laboratory studies have shown that fluorine and iodine atoms participate in analogous catalytic cycles. However, in the Earth's stratosphere, fluorine atoms react rapidly with water and methane to form strongly-bound HF, while organic molecules which contain iodine react so rapidly in the lower atmosphere that they do not reach the stratosphere in significant quantities.
The most pronounced decrease in ozone has been in the lower stratosphere. However, the ozone hole is most usually measured not in terms of ozone concentrations at these levels (which are typically of a few parts per million) but by reduction in the total column ozone, above a point on the Earth's surface, which is normally expressed in Dobson units, abbreviated as "DU". Marked decreases in column ozone in the Antarctic spring and early summer compared to the early 1970s and before have been observed using instruments such as the Total Ozone Mapping Spectrometer (TOMS).
Reductions of up to 70% in the ozone column observed in the austral (southern hemispheric) spring over Antarctica and first reported in 1985 (Farman et al 1985) are continuing. Through the 1990s, total column ozone in September and October have continued to be 40–50% lower than pre-ozone-hole values. In the Arctic the amount lost is more variable year-to-year than in the Antarctic. The greatest declines, up to 30%, are in the winter and spring, when the stratosphere is colder.
Reactions that take place on polar stratospheric clouds (PSCs) play an important role in enhancing ozone depletion. PSCs form more readily in the extreme cold of Antarctic stratosphere. This is why ozone holes first formed, and are deeper, over Antarctica. Early models failed to take PSCs into account and predicted a gradual global depletion, which is why the sudden Antarctic ozone hole was such a surprise to many scientists.
In middle latitudes it is preferable to speak of ozone depletion rather than holes. Declines are about 3% below pre-1980 values for 35–60°N and about 6% for 35–60°S. In the tropics, there are no significant trends.
Ozone depletion also explains much of the observed reduction in stratospheric and upper tropospheric temperatures. The source of the warmth of the stratosphere is the absorption of UV radiation by ozone, hence reduced ozone leads to cooling. Some stratospheric cooling is also predicted from increases in greenhouse gases such as CO2; however the ozone-induced cooling appears to be dominant.
The Antarctic ozone hole is an area of the Antarctic stratosphere in which the recent ozone levels have dropped to as low as 33% of their pre-1975 values. The ozone hole occurs during the Antarctic spring, from September to early December, as strong westerly winds start to circulate around the continent and create an atmospheric container. Within this "polar vortex", over 50% of the lower stratospheric ozone is destroyed during the Antarctic spring.
As explained above, the overall cause of ozone depletion is the presence of chlorine-containing source gases (primarily CFCs and related halocarbons). In the presence of UV light, these gases dissociate, releasing chlorine atoms, which then go on to catalyze ozone destruction. The Cl-catalyzed ozone depletion can take place in the gas phase, but it is dramatically enhanced in the presence of polar stratospheric clouds (PSCs).
These polar stratospheric clouds form during winter, in the extreme cold. Polar winters are dark, consisting of 3 months without solar radiation (sunlight). Not only lack of sunlight contributes to a decrease in temperature but also the “polar vortex” traps and chills air. Temperatures hover around or below -80 °C. These low temperatures form cloud particles and are composed of either nitric acid (Type I PSC) or ice (Type II PSC). Both types provide surfaces for chemical reactions that lead to ozone destruction.
The photochemical processes involved are complex but well understood. The key observation is that, ordinarily, most of the chlorine in the stratosphere resides in stable "reservoir" compounds, primarily hydrogen chloride (HCl) and chlorine nitrate (ClONO2). During the Antarctic winter and spring, however, reactions on the surface of the polar stratospheric cloud particles convert these "reservoir" compounds into reactive free radicals (Cl and ClO). The clouds can also remove NO2 from the atmosphere by converting it to nitric acid, which prevents the newly formed ClO from being converted back into ClONO2.
The role of sunlight in ozone depletion is the reason why the Antarctic ozone depletion is greatest during spring. During winter, even though PSCs are at their most abundant, there is no light over the pole to drive the chemical reactions. During the spring, however, the sun comes out, providing energy to drive photochemical reactions, and melt the polar stratospheric clouds, releasing the trapped compounds.
Most of the ozone that is destroyed is in the lower stratosphere, in contrast to the much smaller ozone depletion through homogeneous gas phase reactions, which occurs primarily in the upper stratosphere.
Warming temperatures near the end of spring break up the vortex around mid-December. As warm, ozone-rich air flows in from lower latitudes, the PSCs are destroyed, the ozone depletion process shuts down, and the ozone hole heals.
Since the ozone layer absorbs UVB ultraviolet light from the Sun, ozone layer depletion is expected to increase surface UVB levels, which could lead to damage, including increases in skin cancer. This was the reason for the Montreal Protocol. Although decreases in stratospheric ozone are well-tied to CFCs and there are good theoretical reasons to believe that decreases in ozone will lead to increases in surface UVB, there is no direct observational evidence linking ozone depletion to higher incidence of skin cancer in human beings. This is partly due to the fact that UVA, which has also been implicated in some forms of skin cancer, is not absorbed by ozone, and it is nearly impossible to control statistics for lifestyle changes in the populace.
Ozone, while a minority constituent in the earth's atmosphere, is responsible for most of the absorption of UVB radiation. The amount of UVB radiation that penetrates through the ozone layer decreases exponentially with the slant-path thickness/density of the layer. Correspondingly, a decrease in atmospheric ozone is expected to give rise to significantly increased levels of UVB near the surface.
Increases in surface UVB due to the ozone hole can be partially inferred by radiative transfer model calculations, but cannot be calculated from direct measurements because of the lack of reliable historical (pre-ozone-hole) surface UV data, although more recent surface UV observation measurement programmes exist (e.g. at Lauder, New Zealand).
Because it is this same UV radiation that creates ozone in the ozone layer from O2 (regular oxygen) in the first place, a reduction in stratospheric ozone would actually tend to increase photochemical production of ozone at lower levels (in the troposphere), although the overall observed trends in total column ozone still show a decrease, largely because ozone produced lower down has a naturally shorter photochemical lifetime, so it is destroyed before the concentrations could reach a level which would compensate for the ozone reduction higher up.
Biological effects of increased UV
The main public concern regarding the ozone hole has been the effects of surface UV on human health. So far, ozone depletion in most locations has been typically a few percent. Were the high levels of depletion seen in the ozone hole ever to be common across the globe, the effects could be substantially more dramatic. As the ozone hole over Antarctica has in some instances grown so large as to reach southern parts of Australia and New Zealand, environmentalists have been concerned that the increase in surface UV could be significant.
Effects on Humans
UVB (the higher energy UV radiation absorbed by ozone) is generally accepted to be a contributory factor to skin cancer. In addition, increased surface UV leads to increased tropospheric ozone, which is a health risk to humans. The increased surface UV also represents an increase in the vitamin D synthetic capacity of the sunlight. The cancer preventive effects of vitamin D represent a possible beneficial effect of ozone depletion. In terms of health costs, the possible benefits of increased UV irradiance may outweigh the burden.
1. Basal and Squamous Cell Carcinomas -- The most common forms of skin cancer in humans, basal and squamous cell carcinomas, have been strongly linked to UVB exposure. The mechanism by which UVB induces these cancers is well understood — absorption of UVB radiation causes the pyrimidine bases in the DNA molecule to form dimers, resulting in transcription errors when the DNA replicates. These cancers are relatively mild and rarely fatal, although the treatment of squamous cell carcinoma sometimes requires extensive reconstructive surgery. By combining epidemiological data with results of animal studies, scientists have estimated that a one percent decrease in stratospheric ozone would increase the incidence of these cancers by 2%.
2. Malignant Melanoma -- Another form of skin cancer, malignant melanoma, is much less common but far more dangerous, being lethal in about 15% - 20% of the cases diagnosed. The relationship between malignant melanoma and ultraviolet exposure is not yet well understood, but it appears that both UVB and UVA are involved. Experiments on fish suggest that 90 to 95% of malignant melanomas may be due to UVA and visible radiation whereas experiments on opossums suggest a larger role for UVB. Because of this uncertainty, it is difficult to estimate the impact of ozone depletion on melanoma incidence. One study showed that a 10% increase in UVB radiation was associated with a 19% increase in melanomas for men and 16% for women.

Ozone Production
Motor vehicles produce exhaust gases containing oxides of nitrogen such as nitrogen dioxide (NO2) and nitric oxide (NO).
At the high temperatures of the car's combustion chamber (cylinder), nitrogen and oxygen from the air react to form nitric oxide (NO):
N2(g) + O2(g) -----> 2NO(g)
Some of the nitric oxide (NO) reacts with oxygen to form nitrogen dioxide (NO2):
2NO(g) + O2(g) -----> 2NO2(g)
The mixture of nitric oxide (NO) and nitrogen dioxide (NO2) is sometimes referred to as NOx.
When the nitrogen dioxide (NO2) concentration is well above clean air levels and there is plenty of sunlight, then an oxygen atom splits off from the nitrogen dioxide molecule:
NO2(g)    sunlight---------->    NO(g)    +    O(g)
This oxygen atom (O) can react with oxygen molecules (O2) in the air to form ozone (O3): O + O2 -----> O3
Nitric oxide can remove ozone by reacting with it to form nitrogen dioxide (NO2) and oxygen (O2): NO(g) + O3(g) -----> NO2(g) + O2(g)
When the ratio of NO2 to NO is greater than 3, the formation of ozone is the dominant reaction. If the ratio is less than 0.3, then the nitric oxide reaction destroys the ozone at about the same rate as it is formed, keeping the ozone concentration below harmful levels.
The reaction of hydrocarbons (unburnt petrol) with nitric oxide and oxygen produce nitrogen dioxide also in the presence of sunlight, increasing the ratio of nitrogen dioxide to nitric oxide.

Module IV - Air Pollution

Air Pollution, contamination of the atmosphere by gaseous, liquid, or solid wastes or by-products that can endanger human health and the health and welfare of plants and animals, or can attack materials, reduce visibility, or produce undesirable odours.

Air Pollutant : Any substance in air that could, in high enough concentration, harm man, other animals, vegetation, or material. Pollutants may include almost any natural or artificial composition of airborne matter capable of being airborne. They may be in the form of solid particles, liquid droplets, gases, or in combination thereof. Generally, they fall into two main groups: (1) those emitted directly from identifiable sources and (2) those produced in the air by interaction between two or more primary pollutants, or by reaction with normal atmospheric constituents, with or without photoactivation. Exclusive of pollen, fog, and dust, which are of natural origin, about 100 contaminants have been identified and fall into the following categories: solids, sulfur compounds, volatile organic chemicals (VOC), nitrogen compounds, oxygen compounds, halogen compounds, radioactive compounds, and odors.
Worldwide air pollution is responsible for large numbers of deaths and cases of respiratory disease. While major stationary sources are often identified with air pollution, the greatest source of emissions is actually mobile sources, mainly automobiles. Gases such as carbon dioxide, which contribute to global warming, have recently gained recognition as pollutants by some scientists. Others recognize the gas as being essential to life, and therefore incapable of being classed as a pollutant.

Pollutants
There are many substances in the air which may impair the health of plants and animals (including humans), or reduce visibility. These arise both from natural processes and human activity. Substances not naturally found in the air or at greater concentrations or in different locations from usual are referred to as 'pollutants'.

Pollutants can be classified as either primary or secondary.

Primary pollutants are substances directly produced by a process, such as ash from a volcanic eruption or the carbon monoxide gas from a motor vehicle exhaust.

Secondary pollutants are not emitted. Rather, they form in the air when primary pollutants react or interact. An important example of a secondary pollutant is ground level ozone - one of the many secondary pollutants that make up photochemical smog.
Note that some pollutants may be both primary and secondary: that is, they are both emitted directly and formed from other primary pollutants.

Major primary pollutants produced by human activity include:

Sulfur oxides (SOx) especially sulfur dioxide, Nitrogen oxides (NOx) especially nitrogen dioxide, Carbon monoxide (CO), Carbon dioxide (CO2), a greenhouse gas.
Volatile organic compounds (VOC), such as hydrocarbon fuel vapors and solvents.
Particulate matter (PM), such as smoke and dust. PM10 is used to describe suspended particles 10 microns in diameter and smaller, and PM2.5 has a maximum particle size of 2.5 microns.
Metal oxides, especially those of lead, and to a lesser degree cadmium, copper, and iron
Chlorofluorocarbons (CFCs), harmful to the ozone layer.
Ammonia (NH3) , Odors, such as from garbage, sewage, and industrial processes.
Secondary pollutants include:
Particulate matter formed from gaseous primary pollutants and compounds in photochemical smog, such as nitrogen dioxide, Ground level ozone (O3), Peroxyacetyl nitrate (PAN)

Anthropogenic sources (human activity) related to burning different kinds of fuel
"Stationary Sources" as smoke stacks of power plants, manufacturing facilities, municipal waste incinerators
"Mobile Sources" as motor vehicles, aircraft etc., Combustion-fired power plants
Controlled burn practices used in agriculture and forestry management, Motor vehicles generating air pollution emissions, Marine vessels, such as container ships or cruise ships, and related port air pollution, Burning wood, fireplaces, stoves, furnaces and incinerators
Other anthropogenic sources
Oil refining, power plant operation and industrial activity in general, Chemicals, dust and crop waste burning in farming, (see Dust Bowl), Fumes from paint, hair spray, varnish, aerosol sprays and other solvents, Waste deposition in landfills, which generate methane.
Military uses, such as nuclear weapons, toxic gases, germ warfare and rocketry.
Natural sources
Dust from natural sources, usually large areas of land with little or no vegetation.
Methane, emitted by the digestion of food by animals, for example cattle.
Radon gas from radioactive decay within the Earth's crust.
Smoke and carbon monoxide from wildfires.
Volcanic activity, which produce sulfur, chlorine, and ash particulates. 


Pollutants

A substance in the air that can be adverse to humans and the environment is known as an air pollutant. Pollutants can be in the form of solid particles, liquid droplets, or gases. In addition, they may be natural or man-made. Pollutants can be classified as primary or secondary. Usually, primary pollutants are directly produced from a process, such as ash from a volcanic eruption, the carbon monoxide gas from a motor vehicle exhaust or sulfur dioxide released from factories. Secondary pollutants are not emitted directly. Rather, they form in the air when primary pollutants react or interact. An important example of a secondary pollutant is ground level ozone — one of the many secondary pollutants that make up photochemical smog. Some pollutants may be both primary and secondary: that is, they are both emitted directly and formed from other primary pollutants.

Major primary pollutants produced by human activity include:

    Sulfur oxides (SOx) - especially sulfur dioxide, a chemical compound with the formula SO2. SO2 is produced by volcanoes and in various industrial processes. Since coal and petroleum often contain sulfur compounds, their combustion generates sulfur dioxide. Further oxidation of SO2, usually in the presence of a catalyst such as NO2, forms H2SO4, and thus acid rain. This is one of the causes for concern over the environmental impact of the use of these fuels as power sources.
    Nitrogen oxides (NOx) - especially nitrogen dioxide are expelled from high temperature combustion, and are also produced naturally during thunderstorms by electric discharge. Can be seen as the brown haze dome above or plume downwind of cities. Nitrogen dioxide is the chemical compound with the formula NO2. It is one of the several nitrogen oxides. This reddish-brown toxic gas has a characteristic sharp, biting odor. NO2 is one of the most prominent air pollutants.
    Carbon monoxide (CO)- is a colourless, odourless, non-irritating but very poisonous gas. It is a product by incomplete combustion of fuel such as natural gas, coal or wood. Vehicular exhaust is a major source of carbon monoxide.

    Volatile organic compounds - VOCs are an important outdoor air pollutant. In this field they are often divided into the separate categories of methane (CH4) and non-methane (NMVOCs). Methane is an extremely efficient greenhouse gas which contributes to enhanced global warming. Other hydrocarbon VOCs are also significant greenhouse gases via their role in creating ozone and in prolonging the life of methane in the atmosphere, although the effect varies depending on local air quality. Within the NMVOCs, the aromatic compounds benzene, toluene and xylene are suspected carcinogens and may lead to leukemia through prolonged exposure. 1,3-butadiene is another dangerous compound which is often associated with industrial uses.

    Particulates, alternatively referred to as particulate matter (PM), atmospheric particulate matter, or fine particles, are tiny particles of solid or liquid suspended in a gas. In contrast, aerosol refers to particles and the gas together. Sources of particulates can be man made or natural. Some particulates occur naturally, originating from volcanoes, dust storms, forest and grassland fires, living vegetation, and sea spray. Human activities, such as the burning of fossil fuels in vehicles, power plants and various industrial processes also generate significant amounts of aerosols. Averaged over the globe, anthropogenic aerosols—those made by human activities—currently account for about 10 percent of the total amount of aerosols in our atmosphere. Increased levels of fine particles in the air are linked to health hazards such as heart disease, altered lung function and lung cancer.

    Persistent free radicals connected to airborne fine particles could cause cardiopulmonary disease.

    Toxic metals, such as lead and mercury, especially their compounds.
    Chlorofluorocarbons (CFCs) - harmful to the ozone layer emitted from products currently banned from use.
    Ammonia (NH3) - emitted from agricultural processes. Ammonia is a compound with the formula NH3. It is normally encountered as a gas with a characteristic pungent odor. Ammonia contributes significantly to the nutritional needs of terrestrial organisms by serving as a precursor to foodstuffs and fertilizers. Ammonia, either directly or indirectly, is also a building block for the synthesis of many pharmaceuticals. Although in wide use, ammonia is both caustic and hazardous.
    Odors — such as from garbage, sewage, and industrial processes
    Radioactive pollutants - produced by nuclear explosions, nuclear events, war explosives, and natural processes such as the radioactive decay of radon.

Secondary pollutants include:

    Particulates created from gaseous primary pollutants and compounds in photochemical smog. Smog is a kind of air pollution; the word "smog" is a portmanteau of smoke and fog. Classic smog results from large amounts of coal burning in an area caused by a mixture of smoke and sulfur dioxide. Modern smog does not usually come from coal but from vehicular and industrial emissions that are acted on in the atmosphere by ultraviolet light from the sun to form secondary pollutants that also combine with the primary emissions to form photochemical smog.
    Ground level ozone (O3) formed from NOx and VOCs. Ozone (O3) is a key constituent of the troposphere. It is also an important constituent of certain regions of the stratosphere commonly known as the Ozone layer. Photochemical and chemical reactions involving it drive many of the chemical processes that occur in the atmosphere by day and by night. At abnormally high concentrations brought about by human activities (largely the combustion of fossil fuel), it is a pollutant, and a constituent of smog.
    Peroxyacetyl nitrate (PAN) - similarly formed from NOx and VOCs.

Minor air pollutants include:

    A large number of minor hazardous air pollutants. Some of these are regulated in USA under the Clean Air Act and in Europe under the Air Framework Directive
    A variety of persistent organic pollutants, which can attach to particulates

Persistent organic pollutants (POPs) are organic compounds that are resistant to environmental degradation through chemical, biological, and photolytic processes. Because of this, they have been observed to persist in the environment, to be capable of long-range transport, bioaccumulate in human and animal tissue, biomagnify in food chains, and to have potential significant impacts on human health and the environment.


Major air pollutants and their associated health hazards


Name of pollutant
Health impacts
RSPM (Respirable Particulate Matter)
Respiratory illness, including chronic bronchitis and asthma; heart diseases.
SO2
Heart diseases; respiratory problems including pulmonary emphysema, cancer, eye burning, headache, etc.
NO2
Lung irritation, viral infection, airway resistance, chest tightness, etc.
SPM (Suspended Particulate Matter)
Pneumoconiosis, restrictive lung diseases, asthma, cancer, etc.
Benzene
It causes immunotoxicity, carcinogenicity, asthma, anemia, unconsciousness etc.
Ozone
Impaired lung function, chest pains, coughing, irritation of eyes, nose etc.
CO
CO poisoning cause cherry lips, unconsciousness, death by asphyxiation etc.
Lead
It causes decreased haemoglobin synthesis, anemia, damage the nervous and renal (kidney) systems etc.